College students' employability is a hotspot problem of educational, social community and managements, and it is very necessary to research the characteristics of university students' employability and its relationship with emotional intelligence this study chose 4 colleges, 900 college students in different grades and different professional as the research object. Analyze the characteristics of college students' employability and its relationship with emotional intelligence by using the method of correlation analysis, regression analysis. In terms of successful employment, the successful employability is increased with the increase of grad. In maintaining employment, seniors maintain employability is significantly higher than freshman. Science and engineering students’ employability is higher than the liberal art and the art students. The correlation of emotional intelligence and employability is significant, and can well predict the employability.