Journal of Chemical and Pharmaceutical Research (ISSN : 0975-7384)

header
Reach Us reach to JOCPR whatsapp-JOCPR +44 1625708989
All submissions of the EM system will be redirected to Online Manuscript Submission System. Authors are requested to submit articles directly to Online Manuscript Submission System of respective journal.

Original Articles: 2016 Vol: 8 Issue: 3

Synthesis and characterization of Hg complex with 1,4-bis([1,10]phenanthroline-[5,6-d]imidazol-2-yl)benzene

Abstract

A new Hg(II) complex of the type [(  -BPIB){Hg(NO3)2}2](1)that BPIB = 1,4-bis([1,10] phenanthrolin-[5,6- d]imidazol-2-yl)benzene has been synthesized and characterized using FT-IR, UV-vis and1 H-NMR spectroscopies. Also electrochemical behavior of complex (1)was studied by Cyclic Voltammetric method. The FT-IR results showed that the ligand was coordinated to metal center. Electronic spectra of this complex was recorded in the DMSO solution. These spectra confirm the intraligand transition bands (π→π*), (n→π*) in UV region. The UV-vis spectrum of title complex don't show any d d transition for central ion. Electrochemical data of this complex showed quasi-reversible waves attributed to redox BPIB ligand

http://sacs17.amberton.edu/

rtp slot demo