Journal of Chemical and Pharmaceutical Research (ISSN : 0975-7384)

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Original Articles: 2015 Vol: 7 Issue: 10

Kinetic studies on the oxidation of benzyl alcohol by hypochlorite in aqueous acetic medium

Abstract

Kinetics of the oxidation of benzyl alcohol by hypo chlorite ion has been studied in acetic acid-water medium. The reaction showed first order dependence on both [sub strate] and [oxidant]. The reaction failed to induc e the polymerisation of added acrylonitile which rules ou t the involvement of any radical intermediate durin g the reaction. The rate of reaction is found to decrease with increase in dielectric constant of the medium . Benzalehyde was obtained as the product with high yield and no traces of benzoic acid were detected. Thermodynamic parameters were determined and a suitable mechanism is proposed in concordance with the obtained resul ts.